Epic Quest Bio The case files
Case No. 121 · the exotic forty · have you seen this molecule?

Dimolybdenum quintuple bond

two metals, five bonds

File sealed

The detectives are still writing this one up. The poster and the facts are below; the film and the interrogation room open soon.

Booking photographs

Dimolybdenum quintuple bond, front view, against a height chart in nanometers
FRONT
Dimolybdenum quintuple bond, side view
SIDE · COD 4104984

The suspect, from its real atomic coordinates. Drag to turn it. Height chart in nanometers, ruled every 0.1 nm. The red crystal it was measured in was about three hundred thousand times wider.

Rap sheet

Answers to
Mo2[HC(NAr)2]2. “Compound 3” to friends.
Bonds
Five: one sigma, two pi, two delta. Ten electrons.
Height
1.1 nm, standing on its bond.
Weight
1.5 zeptograms
Oxidation state
+1 per molybdenum: five d electrons each, all bonding.
Bond length
0.2019 nm, 7 pm shorter than the quadruple bond it came from.
Record
Debuted as the shortest metal–metal bond past the first row, bar a twin.
Last seen
As red crystals, in a lab in Taiwan.
1,600,000,000,000,000

of them in the red flake of crystal that showed its bond to X-rays, give or take.
You’ve never seen one.

CASE FILE: Tsai, Y.-C. et al. (2009) Journey from Mo−Mo Quadruple Bonds to Quintuple Bonds. J. Am. Chem. Soc. 131, 12534–12535.

The poster on the street

The wanted poster for Dimolybdenum quintuple bond

This is the photocopied wanted poster for Dimolybdenum quintuple bond, No. 121 of the exotic forty. They were made for noticeboards around Boston, Cambridge and the rest of the east coast.

Found one? Scan its QR code with your phone. If you're a signed-in player, the sighting goes on your record with +1 XP.

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